92295-85-7Relevant academic research and scientific papers
METHODS OF PREPARATION OF AMINOBORANES AND APPLICATIONS FOR BORYLATION AND SUZUKI COUPLING
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Paragraph 0088, (2022/03/02)
The present invention relates to a process for the preparation of aminoboranes (RR′N—BH2), and aminoborane-amine complexes (RR′N—BH2:NRR′R″), wherein R, and R′ of the aminoborane can be the same or different alkyl groups, and R, R′, and R″ of the amine complex can be the same or different alkyl groups or hydrogen. The dialkylaminoboranes have been utilized for the preparation of aryl and alkenylboronate esters via dehaloborylation of the corresponding aryl or alkenyl halides, followed by treatment with alcohols or diols. The process and the products thereof are within the scope of this disclosure.
Stoichiometric reactions and catalytic dehydrogenations of amine-boranes with calcium aryloxide
Zheng, Xizhou,Huang, Jiasu,Yao, Yingming,Xu, Xin
supporting information, p. 9152 - 9155 (2019/08/07)
Catalysis with the main-group metal calcium conventionally relies on σ-bond metathesis to initiate the reactions. Here, we report a calcium aryloxide based on the tridentate β-diketiminato ligand, which shows transition-metal-like reactivity with dialkyla
