923013-40-5Relevant academic research and scientific papers
Synthesis, characterization and thermal behaviour of ZnS4P 2 chromophore as prototype
Nami, Shahab A. A.,Siddiqi,Chebude, Yonas
, p. 1139 - 1143 (2007/10/03)
Complexes of the type M(PPh3)2(dtc)2 where M = Co(II), Ni(II), Zn(II) and Hg(II), PPh3 = triphenylphosphine and dtc = sodium diethyldithiocarbamate, have been synthesized and characterized by elemental analysis, IR, UV-vis spectroscopy, TGA/DSC, magnetic moment and conductivity measurements. On the basis of these studies, an octahedral geometry has been proposed for all the complexes. The Zn-complex exhibits two-step thermogram leading to the formation of ZnS4 as the end product at 900°C. Symmetrical bidentate coordination of the dithiocarbamato group has been observed in all the cases. Conductivity measurements of 1 mM solution of the complexes in DMSO show them to be non-electrolytes.
