92328-83-1Relevant articles and documents
Anti-Markovnikov Addition of Anilines to Aliphatic Terminal Alkynes Catalyzed by an 8-Quinolinolato Rhodium Complex
Morimoto, Yoshihiko,Kochi, Takuya,Kakiuchi, Fumitoshi
, (2021/10/01)
Anti-Markovnikov addition of anilines to aliphatic terminal alkynes proceeded using an 8-quinolinolato rhodium/phosphine catalyst system. The use of a strong organic base, 1,1,3,3,–tetramethylguanidine, in the catalyst system enabled the formation of the aldimine products. Substrates with various functional groups including polar groups such as a phenolic hydroxy group are applicable to the hydroamination.
Site-Selective C–H Benzylation of Alkanes with N-Triftosylhydrazones Leading to Alkyl Aromatics
Anderson, Edward A.,Bi, Xihe,Cao, Shanshan,Liu, Zhaohong,Wu, Jiayi,Yi, Fanhua,Yu, Weijie
, p. 2110 - 2124 (2020/08/05)
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Bis(2-cycloazylindolyl)titanium Complexes: Synthesis, Characterization, and the Catalytic Behaviors towards Hydroamination and Ring-opening Polymerization of ε-Caprolactone
Zhao, Jing-Jing,Pei, Hao,Chen, Yan-Mei,Lu, Ning,Liu, Jin-Na,Hu, Jin-Fa,Liu, Wei,Li, Wu,Li, Yahong
, p. 1322 - 1328 (2015/06/30)
The ligands 2-pyrazol-1-yl-1H-indole (HL1) and 2-1,2,4-triazol-1-yl-1H-indole (HL2) individually reacted with Ti(NMe2)4 in tetrahydrofuran to form the corresponding complexes Ti(L1)2(NMe2)2 (1) and Ti