923293-53-2Relevant academic research and scientific papers
Synthesis of unnatural α-amino acid derivatives via a three-component coupling method utilizing an allylpalladium umpolung
Hopkins, Chad D.,Malinakova, Helena C.
, p. 3558 - 3566 (2008/09/19)
Highly substituted unnatural α-amino esters, for example, ethyl 3-alkyl-4-(aryl or vinyl)-2-(N-4-methoxyphenylamine)pent-4-enoates were prepared in a regiocontrolled and diastereoselective manner via Pd(II)-catalyzed three-component coupling of boronic ac
Allylpalladium umpolung in the three-component coupling synthesis of homoallylic amines
Hopkins, Chad D.,Malinakova, Helena C.
, p. 5971 - 5974 (2007/10/03)
(Chemical Equation Presented) Homoallylic amines and α-amino esters were prepared via a Pd(II)-catalyzed coupling of boronic acids and 1,2-nonadiene with ethyl iminoacetate or aliphatic, aromatic, and heteroaromatic imines. The allylpalladium umpolung was
