92391-83-8

Basic information

• Product Name: PdCl(P(C₆H₅)3)2C₅H₃NCH₃Cl⁽¹⁺⁾*ClO₄^(1-)=(PdCl(P(C₆H₅)3)2C₅H₃NCH₃Cl)ClO₄
• CAS NO: 92391-83-8
• Molecular Weight: 893.479
• Mol File: 92391-83-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: PdCl(P(C₆H₅)3)2C₅H₃NCH₃Cl⁽¹⁺⁾*ClO₄^(1-)=(PdCl(P(C₆H₅)3)2C₅H₃NCH₃Cl)ClO₄(CAS DataBase Reference)
• NIST Chemistry Reference: PdCl(P(C₆H₅)3)2C₅H₃NCH₃Cl⁽¹⁺⁾*ClO₄^(1-)=(PdCl(P(C₆H₅)3)2C₅H₃NCH₃Cl)ClO₄(92391-83-8)
• EPA Substance Registry System: PdCl(P(C₆H₅)3)2C₅H₃NCH₃Cl⁽¹⁺⁾*ClO₄^(1-)=(PdCl(P(C₆H₅)3)2C₅H₃NCH₃Cl)ClO₄(92391-83-8)

Safety Data

• Hazardous Substances Data: 92391-83-8(Hazardous Substances Data)

Upstream product

• 2402-78-0 2,6-dichloropyridine 
• 14221-01-3 tetrakis(triphenylphosphine) palladium⁽⁰⁾ 

Downstream Products

• 92391-90-7 PdCl(P(C₆H₅)3)2C₅H₃NCH₃OCH₃⁽¹⁺⁾*ClO₄^(1-)=(PdCl(P(C₆H₅)3)2C₅H₃NCH₃OCH₃)ClO₄ 
• 92391-87-2 PdCl(P(C₆H₅(CH₃)2))2C₅H₃CH₃NCl⁽¹⁺⁾*ClO₄^(1-)=PdCl(P(C₆H₅(CH₃)2))2C₅H₃CH₃NClClO₄ 

Relevant articles and documents

PREPARATION AND REACTIONS OF 1-METHYLPYRID-6-ONE-2-YL COMPOUNDS OF PALLADIUM(II) AND PLATINUM(II)

The compounds trans-2>(L)2> (M = Pd, Pt; L = PPh3, PMe2Ph), can be prepared from the reaction of the corresponding 1-methyl-6-chloro-2-pyridylium cationic complexes, trans-2>(L)2>ClO4, with a mixture of acetic acid, ethanol, and triethylamine in the molar ratio M/MeCO2H/EtOH/NEt3 of 1/3/3/4.The rate is slow compared to that of the 1-methyl-2-chloropyridinium cation under similar conditions, and is markedly affected by the steric and electronic effects of the trans-MCl(L)2 unit.The novel 1-methylpyrid-6-one-2-yl derivatives have been characterized by conventional spectroscopic techniques and by reactions involving either protonation and methylation of the carbonyl group or migratory insertion of isocyanides into the Pd-C2 bond.