92418-41-2

Basic information

• Product Name: 6-deoxy-1-O-phosphonohexopyranose
• Synonyms: (3,4,5-trihydroxy-6-methyl-tetrahydropyran-2-yl)oxyphosphonic acid
• CAS NO: 92418-41-2
• Molecular Formula: C₆H₁₃O₈P
• Molecular Weight: 244.1364
• Mol File: 92418-41-2.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 519.4°C at 760 mmHg
• Flash Point: 267.9°C
• Density: 1.75g/cm³
• Vapor Pressure: 5.83E-13mmHg at 25°C
• Refractive Index: 1.569
• CAS DataBase Reference: 6-deoxy-1-O-phosphonohexopyranose(CAS DataBase Reference)
• NIST Chemistry Reference: 6-deoxy-1-O-phosphonohexopyranose(92418-41-2)
• EPA Substance Registry System: 6-deoxy-1-O-phosphonohexopyranose(92418-41-2)

Safety Data

• Hazardous Substances Data: 92418-41-2(Hazardous Substances Data)

Upstream product

• 2438-80-4 L-Fucose 
• 57-04-5 dihydroxyacetone phosphate 
• 3913-65-3 2-hydroxypropanal 
• 3913-64-2 2(S)-hydroxypropanal 

Downstream Products

• 3616-21-5 L-fuculose 

Relevant articles and documents

Efficient enzymatic synthesis of l-rhamnulose and l-fuculose

l-Rhamnulose (6-deoxy-l-arabino-2-hexulose) and l-fuculose (6-deoxy-l-lyxo-2-hexulose) were prepared from l-rhamnose and l-fucose by a two-step strategy. In the first reaction step, isomerization of l-rhamnose to l-rhamnulose, or l-fucose to l-fuculose was combined with a targeted phosphorylation reaction catalyzed by l-rhamnulose kinase (RhaB). The by-products (ATP and ADP) were selectively removed by silver nitrate precipitation method. In the second step, the phosphate group was hydrolyzed to produce l-rhamnulose or l-fuculose with purity exceeding 99% in more than 80% yield (gram scale).

Diastereoselektive, enzymatische Aldoladditionen mit L-Rhamnulose- und L-Fuculose-1-phosphat-Aldolasen aus E. coli

-