92427-76-4

Basic information

• Product Name: 1-CHLORO-4-(1-PHENYL-PROPA-1,2-DIENYL)-BENZENE
• Synonyms: 1-CHLORO-4-(1-PHENYL-PROPA-1,2-DIENYL)-BENZENE
• CAS NO: 92427-76-4
• Molecular Formula: C₁₅H₁₁Cl
• Molecular Weight: 226.70084
• Mol File: 92427-76-4.mol
• Article Data: 5

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1-CHLORO-4-(1-PHENYL-PROPA-1,2-DIENYL)-BENZENE(CAS DataBase Reference)
• NIST Chemistry Reference: 1-CHLORO-4-(1-PHENYL-PROPA-1,2-DIENYL)-BENZENE(92427-76-4)
• EPA Substance Registry System: 1-CHLORO-4-(1-PHENYL-PROPA-1,2-DIENYL)-BENZENE(92427-76-4)

Safety Data

• Hazardous Substances Data: 92427-76-4(Hazardous Substances Data)

Usage

Structure

A chlorinated derivative of a benzene ring substituted with a 1-phenylpropa-1,2-dienyl group

Usage

Commonly used in organic synthesis and as a building block in the production of various materials and compounds

Potential applications

May have potential applications in the pharmaceutical and agrochemical industries

Industrial uses

May have industrial uses as a chemical intermediate or in the manufacturing of specialty chemicals.

Upstream product

• 942398-33-6 1-chloro-4-(2,2-dibromo-1-phenylcyclopropyl)benzene 
• 925-90-6 ethylmagnesium bromide 
• 134-85-0 4-chlorobenzophenone 
• 74-86-2 acetylene 
• 304477-62-1 1-chloro-4-(1-phenylprop-1-enyl)benzene 

Relevant articles and documents

A convenient access to allylic triflones with allenes and triflyl chloride in the presence of (EtO)2P(O)H

A simple method for the preparation of allylic triflones from allenes and triflyl chloride in the presence of (EtO)2P(O)H has been developed. The features of this reaction are catalyst-free and simple starting substrates. This method tolerates diverse functional groups and substituted allylic triflones are obtained in moderate to good yields.

Fluorinative Rearrangements of Substituted Phenylallenes Mediated by (Difluoroiodo)toluene: Synthesis of α-(Difluoromethyl)styrenes

Phenylallenes undergo fluorinative rearrangement upon the action of (difluoroiodo)toluene in the presence of 20 mol % BF3?OEt2 to yield α-difluoromethyl styrenes. This unprecedented reaction was entirely chemoselective for the internal allene π bond, and showed remarkable regioselectivity during the fluorination event. Substituted phenylallenes, phenylallenes possessing both phenyl- and α-allenyl substituents, and diphenylallenes were investigated, and good functional-group compatibility was observed throughout. The ease with which allenes can be prepared on a large scale, and the operational simplicity of this reaction allowed us to rapidly access fluorine-containing building blocks that have not been accessed by conventional deoxyfluorination strategies.

Synthesis of terminal allenes through copper-mediated cross-coupling of ethyne with N-tosylhydrazones or α-diazoesters

Ethyne is employed as coupling partner in coppermediated cross-coupling reactions with N-tosylhydrazones and α-diazoacetate, leading to the development of a new synthetic method for terminal allenes. With this novel coupling method, the terminal allenes w