92496-06-5Relevant academic research and scientific papers
Controlled Ni-catalyzed mono- and double-decarbonylations of α-ketothioesters
Zheng, Zhao-Jing,Jiang, Cheng,Shao, Peng-Cheng,Liu, Wen-Fei,Zhao, Tian-Tian,Xu, Peng-Fei,Wei, Hao
, p. 1907 - 1910 (2019)
A method for Ni-catalyzed controlled decarbonylation of α-ketothioesters is described. Mono- and double-decarbonylations, which gave thioesters and thioethers, respectively, were selectively achieved by changing the ligand. A fundamental study of Ni-catalyzed decarbonylation of α-ketothioesters is presented.
Novel and efficient synthesis of sulfur-containing heterocycles using a hypervalent iodine(III) reagent
Kita, Yasuyuki,Egi, Masahiro,Ohtsubo, Makoto,Saiki, Toyokazu,Takada, Takeshi,Tohma, Hirofumi
, p. 2225 - 2226 (1996)
A novel and efficient synthesis of sulfur-containing heterocycles from phenol ethers bearing an alkyl sulfide sidechain using a combined reagent of a hypervalent iodine(III) species and BF3-Et2O is described.
Metal-and oxidant-free electrochemical synthesis of aryl sulfides
Wang, Xin-Xing,Chen, Cheng,Shi, Hai-Zhu,Zhang, Guo-Wei,Tang, Yu,Zhang, Chun-Gu,Wu, Ming-Yu,Feng, Shun
, (2021/02/26)
A metal- and oxidant-free electrochemical synthesis of aryl sulfides was developed through a C–H sulfidation reaction of arenes and disulfides. Compared with traditional organic synthesis methods, this direct electrochemical approach efficiently generates aryl sulfides under catalyst- and oxidant-free conditions with the superiorities of wide substrate compatibility, mild reaction condition and waster free. At room temperature, various aryl thiols could be transformed smoothly in an undivided cell. Based on cyclic voltammetry (CV) and control experiments, the possible reaction mechanism was also proposed. The gram-scale synthesis emphasizes the practicability of this electrochemical strategy.
Diphenyl ethers for tobacco sucker control
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, (2008/06/13)
Diphenyl ethers having the formula STR1 WHERE Y and Z are halogen, alkyl, trifluoromethyl, alkoxy, hydroxy, nitro, cyano, carboxy, carbalkoxy, carbamoyl, or alkylthio, and m and n are 0, 1, 2, or 3, Are useful in controlling undesirable secondary growth in plants, particularly sucker growth in tobacco.
