92497-32-0

Upstream product

• 36901-75-4 (2-bromobenzyl)triphenylphosphonium bromide 
• 104-87-0 4-methyl-benzaldehyde 
• 2039-88-5 2-bromostyrene 
• 1576-35-8 toluene-4-sulfonic acid hydrazide 
• 106-38-7 para-bromotoluene 

Downstream Products

• 25664-47-5 2-(4-methylphenyl)benzo[b]thiophene 
• 1608105-79-8 C₁₉H₂₀O₃ 
• 1608105-45-8 1,1-dimethyl 2-phenyl 2-(2-(4-methylphenylethyl)phenyl)ethene-1,1,2-tricarboxylate 
• 1608105-87-8 C₁₇H₁₆O₃ 
• 1608105-95-8 C₂₃H₂₀O₃ 

Relevant academic research and scientific papers

Hf(OTf)4-Catalyzed highly diastereoselective synthesis of 1,3-disubstituted tetralin derivatives via benzylic C(sp3)-H bond functionalization

We report a highly diastereoselective synthesis of 1,3-disubstituted tetralin derivatives via Lewis acid catalyzed benzylic C(sp3)-H bond functionalization. The employment of Hf(OTf)4 as an acid catalyst was crucial in the reaction,

Open-air oxidative Mizoroki-Heck reaction of arylsulfonyl hydrazides with alkenes

A palladium(ii)-catalyzed oxidative Mizoroki-Heck reaction of arylsulfonyl hydrazides with alkenes was developed employing atmospheric air as the sole oxidant in an open-vessel manner. By using palladium(ii) acetate associating with inexpensive, air-stable and moisture stable pyridine ligand L9 as the catalyst system, the efficiency of the reaction could be significantly enhanced. A wide range of arylsulfonyl hydrazides underwent the oxidative Mizoroki-Heck reaction with alkenes smoothly. Good-to-excellent product yields and excellent regio- and stereoselectivity were achieved. Functional groups such as halo, ester etc. were well-tolerated under these optimized reaction conditions.

Iminophosphine palladium(II) complexes: Synthesis, characterization, and application in Heck cross-coupling reaction of aryl bromides

Palladium(II) complexes containing phosphorus and nitrogen donor atoms (iminophosphine), dichlorido{N-[2-(diphenylphosphino)benzylidene]-2- trifluoromethylaniline}palladium(II) 1, dichlorido{N-[2-(diphenylphosphino) benzylidene]-3-trifluoromethylaniline}palladium(II) 2, dichlorido{N-[2- (diphenylphosphino)benzylidene]-2-methylaniline}palladium(II) 3, dichlorido{N-[2-(diphenylphosphino)benzylidene]-3-methylaniline}palladium(II) 4 have been successfully synthesized and fully characterized by FT-IR and NMR (1H, 31P, 19F, and 13C) spectroscopy techniques. These complexes were first step tested in the reaction of bromobenzene and styrene to determine the optimal coupling reaction conditions and then successfully applied as catalysts for Heck cross-coupling reactions of activated and deactivated aryl bromides with styrene derivatives and several acrylates. Copyright

Catalytic enantioselective C(sp3)H functionalization: Intramolecular benzylic [1,5]-hydride shift

The catalytic asymmetric [1,5]-hydride transfer/cyclization sequence involving benzylic C(sp3)H bond was established, providing tetrahydronaphthalene derivatives in moderate to high yield with up to 69% ee, by employing the copper complex of si

Photochemistry of o-pyrrolylstilbenes and formation of spiro-2H-pyrroles and their rearrangement to dihydroindoles

(Chemical Equation Presented) Excited states of stilbenylpyrroles 1a-1c deactivate by two photochemical processes: cis-trans-isomerization and hydrogen transfer of NH to the stilbene double bond. NH-transfer results in the formation of two quinone dimetha