92506-20-2Relevant academic research and scientific papers
Amidinium based ionic liquids
Dechambenoit, Pierre,Ferlay, Sylvie,Kyritsakas, Nathalie,Hosseini, Mir Wais
, p. 1184 - 1199 (2010/08/08)
Three new series of mono-and bis-cyclic amidinium cations bearing alkyl chains of different length were synthesized. 53 salts were generated upon combining the cations with a variety of anions and their thermal behaviour was investigated. Depending on the structure and the charges state of the cyclic amidinium moiety and the nature of the anion, several of the obtained salts behaved as ionic liquids with their melting point in the range of ca. 25-94 °C.
Cu(ii)-mediated oxidative intermolecular ortho C-H functionalisation using tetrahydropyrimidine as the directing group
Mizuhara, Tsukasa,Inuki, Shinsuke,Oishi, Shinya,Fujii, Nobutaka,Ohno, Hiroaki
supporting information; experimental part, p. 3413 - 3415 (2009/12/26)
Tetrahydropyrimidine works efficiently as a directing group in Cu(ii)-mediated oxidative aromatic C-H functionalisation for the selective introduction of oxygen or nitrogen to the ortho-position.
