92510-04-8Relevant articles and documents
PRENYLATION-CYCLISATION OF GERANYL ACETATE
Julia, Marc,Schmitz, Christian
, p. 2491 - 2500 (2007/10/02)
Conditions have been found for the reaction of α-dimethyl allyl alcohol with geranyl acetate under acid catalysis to give 1,3,3-trimethyl-4-(3-methyl-2-buten-1-yl) 2-acetoxymethyl-1-cyclohexanol.Four isomers have been isolated and their structures determi
SYNTHESE BIOMIMETIQUE DES SESQUE-IONONES α-CIS, α-TRANS ET β
Babin, Didier,Julia, Marc
, p. 1545 - 1550 (2007/10/02)
A prenyl residue has been introduced at C-9 of pseudionone with dimethylcarbinol and formic acid.The distal double bond in the formyl-oxy-ketone was protected by conversion into the corresponding methoxy bromide with NBS/MEOH.Sulfuric acid effected the cy