92511-60-9Relevant academic research and scientific papers
Regioselective Head-to-tail Coupling of Allylic Trialkylstannanes with Allylic Halides under High Pressure
Yamamoto, Yoshinori,Maruyama, Kazuhiro,Matsumoto, Kiyoshi
, p. 548 - 549 (1984)
Allylic trialkylstannanes (1) regioselectively react with allylic halides (2) at room temperature under high pressure (10 kbar) to give head-to-tail coupling products (3) in high yields.
Selective Alkylation and Allylation of Allylic Halides by Tetraorganoidates: Regio- and Stereo-selective Synthesis of Rosefuran and Sesquirosefuran
Araki, Shuki,Jin, Shun-Ji,Butsugan, Yasuo
, p. 549 - 552 (2007/10/02)
Tetraalkylindanes regioselectively alkylate allylic bromides at the α-carbon.In this way, 1,5-dienes have been regio- and stereo-selectively synthesized by the allyl-allyl coupling of allylic bromides and allylic indates, including rosefuran 1 and sequirosefuran 3.
Application of Indium Ate Complexes to Synthetic Chemistry. Selective Conjugate Addition to Enones and Coupling with Allylic Halides
Araki, Shuki,Shimizu, Toshio,Jin, Shun-Ji,Butsugan, Yasuo
, p. 824 - 825 (2007/10/02)
Tetraorganoindium ate complexes, prepared by the addition of organolithium reagents to trialkylindium, reacted with α,β-unsaturated ketones in a 1,4-addition fashion; allylic indates derived from allylic indium sesquihalides coupled with allylic halides regio- and stereo-specifically to give high yields of hed-to-tail 1,5-dienes.
