92516-44-4Relevant academic research and scientific papers
Synthesis of water-tolerant indium homoenolate in aqueous media and its application in the synthesis of 1,4-dicarbonyl compounds via palladium-catalyzed coupling with acid chloride
Shen, Zhi-Liang,Goh, Kelvin Kau Kiat,Cheong, Hao-Lun,Wong, Colin Hong An,Lai, Yin-Chang,Yang, Yong-Sheng,Loh, Teck-Peng
supporting information; experimental part, p. 15852 - 15855 (2011/01/10)
The first water-tolerant, ketone-type indium homoenolate was synthesized via the oxidative addition of In/InCl3 to enones. The reaction proceeds exclusively in aqueous media. Both indium and indium(III) chloride are necessary for the smooth conversion of the reaction. Similar results were obtained when InCl or InCl2 was used in place of In/InCl3. The synthetic utility of the indium homoenolate was demonstrated through the synthesis of 1,4-dicarbonyl compounds via palladium-catalyzed coupling of indium homoenolate with acid chloride.
THE PREPARATION OF 1,4-DICARBONYL COMPOUNDS BY PHOTOREACTION OF KETONES IN THE PRESENCE OF OXIDANTS
Mitani, Michiharu,Tamada, Mamoru,Uehara, Shin-ichi,Koyama, Kikuhiko
, p. 2805 - 2808 (2007/10/02)
Phenyl alkyl ketones were photo-irradiated in the presence of Cr(VI) or Mn(VII) oxidants to yield 1,4-dicarbonyl compounds regiospecifically while 2-octanone gave a regioisomeric mixture of 2,5-, 2,6-, and 2,7-octadiones.
