92540-95-9Relevant academic research and scientific papers
Carbon-to-Nitrogen Rearrangement in N-(Arylsulfonoxy)amines as a Route to Azacyclic Compounds
Hoffman, Robert V.,Buntain, Gregory A.
, p. 3316 - 3321 (2007/10/02)
A series of cyclic amines 1-10 was converted to the N-((p-nitrophenyl)sulfonoxy)amine derivatives with (p-nitrophenyl)sulfonyl peroxide.These compounds rearranged to ring-expanded cyclic imines in fair to good yields.Conversion of the amine to its hydroxy
THE C-ALKYLATION OF NITROALKANE ANIONS BY 1-SUBSTITUTED-2-T-BUTYL-4-PHENYL- AND -2,4-DIPHENYL-5,6-DIHYDROBENZOQUINOLINIUM CATIONS.
Katritzky, Alan R.,Kashmiri, M. Akram,Wittmann, Dieter K.
, p. 1501 - 1510 (2007/10/02)
The N-substituents are transferred from the title cations to the C-atom of nitroalkane anions in high yield at 25-80 deg C in DMSO solution.The title cations are readily available from the appropriate pyrylium cations and primary amines of types RCH2NH2 and RR'CHNH2, allowing a general 2-step method for the preparation of higher nitroalkanes.Spectral properties of a variety of nitroalkanes are discussed.
