925460-41-9Relevant academic research and scientific papers
Lewis acid mediated asymmetric [2,3]-sigmatropic rearrangement of allylic amines. Scope and mechanistic investigation
Blid, Jan,Panknin, Olaf,Tuzina, Pavel,Somfai, Peter
, p. 1294 - 1300 (2007/10/03)
(Chemical Equation Presented) The first asymmetric [2,3]-sigmatropic rearrangement of achiral allylic amines has been realized by quaternization of the amines with an enantiomerically pure diazaborolidine and subsequent treatment with Et3N. The
Ir-catalyzed allylic amination/ring-closing metathesis: A new route to enantioselective synthesis of cyclic β-amino alcohol derivatives
Jun, Hee Lee,Shin, Seunghoon,Kang, Jahyo,Lee, Sang-Gi
, p. 7443 - 7446 (2008/02/11)
(Chemical Equation Presented) Ir-catalyzed allylic aminations of (E)-4-benzyloxy-2-butenyl methyl carbonate with benzylamine using Feringa's (Sa,Sc,Sc)- phosphoramidite as a chiral ligand afforded linear-aminated achiral p
