92549-05-8Relevant articles and documents
Stilbene synthesis through decarboxylative cross-coupling of substituted cinnamic acids with aryl halides
Rameau, Nelly,Russo, Baptiste,Mangematin, Stéphane,Pinel, Catherine,Djakovitch, Laurent
, p. 132 - 143 (2018/05/22)
The Pd-catalyzed decarboxylative cross-coupling reaction between cinnamic acid and aryl iodide derivatives was studied using both homogeneous and heterogeneous Pd-catalysts. It was demonstrated that simple Pd(OAc)2 can catalyze this reaction wi
Catalytic Asymmetric 1,6-Conjugate Addition of para-Quinone Methides: Formation of All-Carbon Quaternary Stereocenters
Wang, Zhaobin,Wong, Yuk Fai,Sun, Jianwei
supporting information, p. 13711 - 13714 (2015/11/11)
Described herein is a general and mild catalytic asymmetric 1,6-conjugate addition of para-quinone methides (p-QMs), a class of challenging reactions with previous limited success. Benefiting from chiral Bronsted acid catalysis, which allows in situ formation of p-QMs, our reaction expands the scope to general p-QMs with various substitution patterns. It also enables efficient intermolecular formation of all-carbon quaternary stereocenters with high enantioselectivity.
