92549-07-0

Upstream product

• 50-00-0 formaldehyd 
• 4237-44-9 2-(1-phenylethyl)phenol 

Downstream Products

• 1582788-14-4 bis[2-{[4-(pent-4-enyloxy)phenylimino]methyl}-6-(1-phenylethyl)phenoxy]titanium(IV) dichloride 
• 1582788-01-9 2-{[4-(pent-4-enyloxy)phenylimino]methyl}-6-(1-phenylethyl)phenol 
• 1582788-18-8 bis[4-bromo-2-{[4-(pent-4-enyloxy)phenylimino]methyl}-6-(1-phenylethyl)phenoxy]titanium(IV) dichloride 
• 1582788-17-7 bis[2-{[4-(pent-4-enyloxy)phenylimino]methyl}-6-(1-phenylethyl)-4-chlorophenoxy]titanium(IV) dichloride 
• 1582788-05-3 4-bromo-2-{[4-(pent-4-enyloxy)phenylimino]methyl}-6-(1-phenylethyl)phenol 
• 1582788-04-2 2-{[4-(pent-4-enyloxy)phenylimino]methyl}-6-(1-phenylethyl)-4-chlorophenol 
• 1582787-88-9 5-bromo-2-hydroxy-3-(1-phenylethyl)benzaldehyde 
• 92435-59-1 2-hydroxy-3-(1-phenylethyl)-5-chlorobenzaldehyde 
• 1400812-17-0 2-[(4-allyloxyphenylimino)methyl]-6-(1-phenylethyl)phenol 
• 1400812-09-0 2-[(3-allyloxyphenylimino)methyl]-6-(1-phenylethyl)phenol 
• 1400811-98-4 2-[(2-allyloxyphenylimino)methyl]-6-(1-phenylethyl)phenol 

Relevant academic research and scientific papers

Design of postmetallocene catalytic systems of arylimine type for olefin polymerization: XVI. Synthesis of (N-aryl)salicylaldimines containing pent-4-enyloxy group and their complexes with titanium(IV) dichloride

Reactions of p-(pent-4-enyloxy)aniline with salicylaldehyde containing versatile substituents in the positions 3 and 5 in an open system without solvent at 130°C afforded a series of (N-aryl)salicylaldimines, which with TiCl2(OPr-i)2 formed complexes of titanium(IV) dichloride L2TiCl2.

Synthesis of salicylaldehydes bearing bulky substituents in the positions 3 and 5

Reaction of 2,4-disubstituted phenols with paraformaldehyde in the presence of SnCl4 and 2,6-lutidine afforded a number of new salicylaldehydes, containing bulky substituents (tert-butyl, 1-phenylethyl, 1-(4-tert- butylphenyl)ethyl, α-cumyl, and trityl) in the positions 3 and 5.