92567-57-2

Upstream product

• 4291-69-4 2,3,4,6-Tetra-O-benzyl-D-glucopyranose 
• 13096-62-3 (3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-((benzyloxy)methyl)tetrahydro-2H-pyran-2-one 

Downstream Products

• 92621-59-5 (3S,4S,5R)-tribenzyloxy-(2R)-benzyloxymethyl-1,7-dioxa-(6S)-spiro<5,5>undec-10-ene 
• 92621-60-8 (3S,4S,5R)-tribenzyloxy-(2R)-benzyloxymethyl-1,7-dioxa-(6S)-spiro<5,5>undecane 
• 92567-59-4 2,3,4,6-tetra-O-benzyl-1-C-(4-hydroxy-1-Z-butenyl)-D-glucopyranose 

Relevant academic research and scientific papers

SYNTHESIS OF A CHIRAL 1,7-DIOXASPIROUNDECENE. A MODEL FOR THE SPIROACETAL SUBUNIT OF AVERMECTIN B1a

The stereocontrolled synthesis of a chiral, polyhydroxy 1,7-dioxaspiroundecene from D-glucose is described.The bicyclic system with a different pattern of substitution can be found in a number of biologically important natural products such as the avermectins and the milbemycins.