92594-30-4Relevant academic research and scientific papers
OXIDATIVE CLEAVAGE OF THE DOUBLE BOND OF 7-DEHYDROCHOLESTEROL ACETATE PEROXIDE
Gumulka, Jerzy,Szczepek, Wojciech J.,Wielogorski, Zbigniew A.
, p. 403 - 411 (2007/10/02)
Ozonolysis of 7-dehydrocholesterol acetate peroxide is described.The structures of diketone 3 and lactol 4 were confirmed by their LAH reduction to triol 7 and tetraol 9, respectively.Moreover, tetraol 9, tetraol 12 and pentaol 14 were obtained from reduction of ozonation products.It has been established that compounds 3 and 4 are formed as a result of rearrangements of the first detectable product of epidioxy 2 ozonation, namely epidioxydialdehyde 16.
