92594-53-1Relevant academic research and scientific papers
One-Pot, Three-Component Approach to Diarylmethylphosphonates: A Direct Entry to Polycyclic Aromatic Systems
Prasad, Sure Siva,Singh, DIleep Kumar,Kim, Ikyon
supporting information, p. 6323 - 6336 (2019/05/24)
A new type of three-component reaction was developed consisting of aldehydes, electron-rich (hetero)arenes, and trialkyl phosphite, which provided facile access to a wide range of diarylmethylphosphonates under mild reaction conditions. Simple one- or two-step synthetic manipulation of the resulting compounds enabled us to reach several polycyclic (hetero)aromatic systems efficiently.
Synthesis and reactivity of substituted alkoxymethylphosphonites and their derivatives
Prishchenko, Andrey A.,Livantsov, Mikhail V.,Novikova, Olga P.,Livantsova, Ludmila I.,Petrosyan, Valery S.
experimental part, p. 281 - 289 (2012/07/28)
Alkoxy-substituted methylphosphonites and their derivatives are prepared using an organomagnesium method of synthesizing the organophosphorus compounds and alkoxymethylation of various PH acids and their derivatives. Also, certain properties of these promising compounds as important precursors of new functionalized organophosphorue compounds with alkoxymethyl fragments are presented.
Direct conversion of acetals to esters with high regioselectivity via O,P-acetals
Maegawa, Tomohiro,Otake, Kazuki,Goto, Akihiro,Fujioka, Hiromichi
, p. 5648 - 5651 (2011/09/15)
A new direct conversion of O,O-acetals to esters via O,P-acetal intermediates was developed. The regioselective cleavage of unsymmetrical cyclic acetals occurred to give the more crowded esters as single isomers.
A FACILE SYNTHESIS OF DIETHYL 1-ALKOXY-1-ARYLMETHANEPHOSPHONATES
Kim, Dae Young,Oh, Dong Young
, p. 859 - 864 (2007/10/02)
1-Alkoxy-1arylmethanephosphonates (3) can be prepared by the reaction of arylaldehyde acetal (2) and diethyl trimethylsilylphosphite (1) in the presence of stannic chloride under mild conditions.
