92596-30-0

Upstream product

• 92596-29-7 (3aR,4S,5R,6aS)-4-(((tert-butyldiphenylsilyl)oxy)methyl)-5-((tetrahydro-2H-pyran-2-yl)oxy)hexahydro-2H-cyclopenta[b]furan-2-one 

Downstream Products

• 92596-32-2 7-[(1R,2S,3R)-2-(tert-Butyl-diphenyl-silanyloxymethyl)-5-formyl-3-(tetrahydro-pyran-2-yloxy)-cyclopentyl]-6-oxo-heptanoic acid methyl ester 
• 92596-31-1 7-[(1S,2S,3R,5S)-2-(tert-Butyl-diphenyl-silanyloxymethyl)-5-hydroxymethyl-3-(tetrahydro-pyran-2-yloxy)-cyclopentyl]-6-hydroxy-heptanoic acid methyl ester 
• 92596-31-1 7-[(1S,2S,3R,5R)-2-(tert-Butyl-diphenyl-silanyloxymethyl)-5-hydroxymethyl-3-(tetrahydro-pyran-2-yloxy)-cyclopentyl]-6-hydroxy-heptanoic acid methyl ester 
• 92596-33-3 5-[(3aS,4S,5R,6aS)-4-(tert-Butyl-diphenyl-silanyloxymethyl)-1,2-dihydroxy-5-(tetrahydro-pyran-2-yloxy)-octahydro-pentalen-2-yl]-pentanoic acid methyl ester 
• 92596-34-4 5-[(1bS,3R,4S,4aS)-4-(tert-Butyl-diphenyl-silanyloxymethyl)-3-(tetrahydro-pyran-2-yloxy)-hexahydro-1-oxa-cyclopropa[a]pentalen-5a-yl]-pentanoic acid methyl ester 
• 92596-35-5 5-[(3aS,5R,6S,6aS)-6-(tert-Butyl-diphenyl-silanyloxymethyl)-5-(tetrahydro-pyran-2-yloxy)-1,3a,4,5,6,6a-hexahydro-pentalen-2-yl]-pentanoic acid methyl ester 
• 88931-51-5 isocarbacyclin 

Relevant academic research and scientific papers

AN IMPROVED ROUTE TO (+)-9(O)-METHANO-Δ6(9Α)-PROSTAGLANDIN-I1 (ISOCARBACYCLIN)

An improved synthesis of the title compound and a synthesis of its derivatives are described, in which the regiospecific transformation of the diene into diol was effectiely achived by using thexylborane.