925977-53-3

Upstream product

• 1027287-68-8 (1R,4S,5S)-4-[2,6-Bis-methoxymethoxy-4-((E)-styryl)-phenyl]-5-isopropenyl-2-methyl-3-trimethylsilanyloxy-cyclohex-2-enol 
• 925977-51-1 (2S,3S,5R,6S)-2-(2,6-bis(methoxymethoxy)-4-styrylphenyl)-5-hydroxy-6-methyl-3-(prop-1-en-2-yl)cyclohexanone 
• 903520-30-9 ((1R,4S,6R)-4-Isopropenyl-1-methyl-7-oxa-bicyclo[4.1.0]hept-2-en-2-yloxy)-trimethyl-silane 
• 925977-52-2 (2S,3S,5R,6S)-2-[2,6-Bis-methoxymethoxy-4-((E)-styryl)-phenyl]-5-(tert-butyl-dimethyl-silanyloxy)-3-isopropenyl-6-methyl-cyclohexanone 

Downstream Products

• 925977-58-8 2-((1S,2S,5S)-2-Isopropenyl-5-methyl-cyclohexyl)-1,3-bis-methoxymethoxy-5-((E)-styryl)-benzene 
• 925977-56-6 (1R,2R,4S,5S)-4-[2,6-Bis-methoxymethoxy-4-((E)-styryl)-phenyl]-5-isopropenyl-2-methyl-cyclohexanol 
• 925977-57-7 Methanesulfonic acid (1R,2R,4S,5S)-4-[2,6-bis-methoxymethoxy-4-((E)-styryl)-phenyl]-5-isopropenyl-2-methyl-cyclohexyl ester 
• 925977-55-5 {(1R,2R,4S,5S)-4-[2,6-Bis-methoxymethoxy-4-((E)-styryl)-phenyl]-5-isopropenyl-2-methyl-cyclohexyloxy}-tert-butyl-dimethyl-silane 
• 925977-54-4 dithiocarbonic acid O-[2-(2,6-bis-methoxymethoxy-4-styryl-phenyl)-5-(tert-butyl-dimethyl-silanyloxy)-3-isopropenyl-6-methyl-cyclohexyl] ester S-methyl ester 

Relevant academic research and scientific papers

A general route to 5,6-seco-hexahydrodibenzopyrans and analogues: first total synthesis of (+)-Machaeridiol B and (+)-Machaeriol B

A general and efficient route for the synthesis of 5,6-seco-hexahydrodibenzopyran and trans-hexahydrodibenzopyran analogues was established, via a highly regio- and stereoselective SN2′ reaction of arylcyanocuprates to enol silyl ether of α,β-e