926020-75-9Relevant academic research and scientific papers
Unexpected formal aryl insertion in a cyclometalated diphenylplatinum (IV) complex: The first seven-membered cyclometalated platinum compound structurally characterized
Font-Bardía, Mercè,Gallego, Carlos,Martinez, Manuel,Solans, Xavier
, p. 3305 - 3307 (2002)
The structural characterization of a seven-membered cyclometalated platinum compound was investigated. In regard with it, the aryl insertion in a cyclometalated diphenylplatinum (IV) complex was studied. The liability of the selenium based ligand enabled the reductive elimination of a C6H6 molecule and the formal aryl insertion of other phenyl ligand in the cyclometalated bond. The crystal structure of the triphenylphosphine derivative was determined by using x-ray analysis.
