926035-87-2Relevant academic research and scientific papers
Chiral aggregates formed from methylated tetraenoic fatty acids: Formation of both antipodes of chiral aggregates from a single enantiomer and time-dependent stereomutation
Ma, Jianguo,Cheon, Hwan-Sung,Kishi, Yoshito
, p. 319 - 322 (2008/02/03)
(Chemical Equation Presented) Formation and behaviors of chiral aggregates of methylated tetraenoic fatty acids (TE-FAs) were reported. In the C-24 TE-FA series, the aggregate prepared by dispersing an ethanol stock solution of C-24 TE-FA 1b into sodium phosphate buffer gave a strong positive Cotton effect, whereas the aggregate prepared from a methanol stock solution gave a negative Cotton effect. In the C-20 TE-FA series, the aggregate prepared from an ethanol stock solution of C-20 TE-FA 2b exhibited time-dependent chirality inversion.
