92611-89-7Relevant academic research and scientific papers
Synthetic Studies on Spiroketal Natural Products. I. A Stereoselective Synthesis of (2R*,5R*)- and (2R*,5S*)-2-Methyl-1,6-dioxaspirodecane
Iwata, Chuzo,Hattori, Kohji,Kuroki, Toshio,Uchida, Shuji,Imanishi, Takeshi
, p. 2909 - 2917 (2007/10/02)
A stereoselective and novel method for construction of the spiroketal moiety is described, as illustrated by a synthesis of (2R*,5R*)- and (2R*,5S*)-2-methyl-1,6-dioxaspirodecane (2A and 2B).The sulfide (7)
A NEW AND FACILE ROUTE TO SPIRO-KETAL SKELETON VIA HIGHLY STEREOSELECTIVE C-O BOND FORMATION BY INTRAMOLECULAR MICHAEL ADDITION TO α,β-UNSATURATED SULFOXIDES
Iwata, Chuzo,Hattori, Kohji,Uchida, Shuji,Imanishi, Takeshi
, p. 2995 - 2998 (2007/10/02)
Diastereoisomerically pure (E)- and (Z)-2-methyl-1,6-dioxaspiro-decane (insect pheromone) was efficiently prepared via a highly stereocontrolled intramolecular Michael addition of hydroxyl group to an unsaturated sulfoxide moiety during the crucial c
