92691-79-7

Basic information

• Product Name: 1,3,4,6-tetra-O-benzyl-α-D-fructofuranose
• Synonyms: 1,3,4,6-tetra-O-benzyl-α-D-fructofuranose
• CAS NO: 92691-79-7
• Molecular Weight: 540.656
• Mol File: 92691-79-7.mol

Chemical Properties

• CAS DataBase Reference: 1,3,4,6-tetra-O-benzyl-α-D-fructofuranose(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3,4,6-tetra-O-benzyl-α-D-fructofuranose(92691-79-7)
• EPA Substance Registry System: 1,3,4,6-tetra-O-benzyl-α-D-fructofuranose(92691-79-7)

Safety Data

• Hazardous Substances Data: 92691-79-7(Hazardous Substances Data)

Upstream product

• 18685-22-8 1,3,4,6-tetra-O-benzyl-β-D-fructofuranosyl 2,3,4,6-tetra-O-benzyl-α-D-glucopyranoside 

Downstream Products

• 111112-49-3 1-(1,3,4,6-tetra-O-benzyl-β-D-fructofuranosyl)-2-propene 
• 28697-73-6 2-(p-nitrobenzoyl)-1,3,4,6-tetra-O-benzyl-D-fructofuranose 

Relevant articles and documents

Preparation of partially benzylated mono-, di-, and trisaccharides by selective cleavage of the β-fructofuranosidic linkage in fully benzylated sucrose and sucrose-related oligosaccharides under acidic conditions

Several partially benzylated mono-, di-, and trisaccharides having an anomeric hydroxyl group were successfully prepared by selective cleavage of the β-fructofuranosidic linkage in fully benzylated sucrose and sucrose-related oligosaccharides derived from lactosucrose, raffinose, melezitose, stachyose, and nystose under acidic conditions using 1:10 75% aqueous sulfuric acid-dioxane at room temperature for 1 h.

Synthesis of D-fructofuranosylpurine nucleosides

The Mitsunobu reaction has been applied to the formation of purine nucleosides of D-fructofuranose. The use of O-benzyl protection results in a predominance of the β-configuration in these novel compounds and both α- and β-D-fructofuranosyladenine are obtained in stereochemically pure form.