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927423-16-3

The complex [(Pt(PCy3))2(μ-η2-HSiPh2)(μ-η2-HSiEt2)] is a diplatinum species featuring bridging hydrosilyl ligands (HSiPh2 and HSiEt2) coordinated in a μ-η2 fashion. It is formed through ligand exchange involving Si-H bond cleavage and formation, where the original bridging diethylsilyl ligands in [{Pt(PCy3)}2(μ-η2-HSiEt2)2] react with diphenylsilane (H2SiPh2) to yield the mixed-ligand complex. This transformation highlights the reactivity of platinum silyl complexes in Si-H bond activation and ligand substitution processes.

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  • 927423-16-3 Structure

  • Basic information

    1. Product Name: [(Pt(PCy3))2(μ-η2-HSiPh2)(μ-η2-HSiEt2)]
    2. Synonyms:
    3. CAS NO:927423-16-3
    4. Molecular Formula:
    5. Molecular Weight: 1221.55
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 927423-16-3.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: [(Pt(PCy3))2(μ-η2-HSiPh2)(μ-η2-HSiEt2)](CAS DataBase Reference)
    10. NIST Chemistry Reference: [(Pt(PCy3))2(μ-η2-HSiPh2)(μ-η2-HSiEt2)](927423-16-3)
    11. EPA Substance Registry System: [(Pt(PCy3))2(μ-η2-HSiPh2)(μ-η2-HSiEt2)](927423-16-3)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 927423-16-3(Hazardous Substances Data)

927423-16-3 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 927423-16-3 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 9,2,7,4,2 and 3 respectively; the second part has 2 digits, 1 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 927423-16:
(8*9)+(7*2)+(6*7)+(5*4)+(4*2)+(3*3)+(2*1)+(1*6)=173
173 % 10 = 3
So 927423-16-3 is a valid CAS Registry Number.

927423-16-3Downstream Products

927423-16-3Relevant articles and documents

Ligand exchange of diplatinum complexes with bridging silyl ligands involving Si-H bond cleavage and formation

Tanabe, Makoto,Ito, Daisuke,Osakada, Kohtaro

, p. 2258 - 2267 (2008)

Reactions of excess H2SiEt2 and H 2SiHex2 with [Pt(PCy3)2] at room temperature form mononuclear cis-hydrido(silyl)platinum complexes, cis-[Pt(H)(SiHR2)(PCy3)2/su

Diplatinum complexes with bridging silyl ligands. Si-H bond activation of μ-silyl ligand leading to a new platinum complex with bridging silylene and silane ligands

Tanabe, Makoto,Ito, Daisuke,Osakada, Kohtaro

, p. 459 - 462 (2007)

A diplatinum complex with bridging diethylsilyl ligands, [{Pt(PCy 3)}2(μ-η2-HSiEt2) 2] (1), reacted with an excess of H2SiPH2 to yield [{Pt(PCy3)}2(ν-η

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