92753-11-2

Upstream product

• 5599-27-9 dichloro(dimesityl)silane 
• 83115-12-2 (2,4,6-tri-tert-butylphenyl)phosphine 
• 83115-13-3 lithium 2,4,6-tris(tert-butyl)phenylphosphide 

Downstream Products

• 92753-13-4 [Methoxy-bis-(2,4,6-trimethyl-phenyl)-silanyl]-(2,4,6-tri-tert-butyl-phenyl)-phosphane 
• 92753-10-1 P-(2,4,6-tri-tert-butylphenyl)-Si,Si-bis(2,4,6-trimethylphenyl)phosphasilene 
• 92753-12-3 [Butyl-bis-(2,4,6-trimethyl-phenyl)-silanyl]-(2,4,6-tri-tert-butyl-phenyl)-phosphane 

Relevant academic research and scientific papers

2,4,6-TRI-tert-BUTYLPHENYLPHOSPHENE-DIMESITYLSILENE; THE FIRST PHOSPHASILAALKENE

The title compound (1) was prepared from chlorodimesitylsilyl-2,4,6-tri-tert-butylphenylphosphine (4) with n-butyllithium and characterized by its spectral data and by its chemical conversion with methanol to adduct 6.

PHOSPHASILAETHENES

The synthesis, stability, and spectroscopic properties of several phosphasilaethenes ArP=SiR'R'' are described.It is concluded that the P=Si bond is a typical p(?)-p(?) bond which is highly polarized (Pδ-, Siδ+).