92760-17-3

Basic information

• Product Name: (1R,5S,8R,9R)-4,4,8-trimethylbicyclo<6.3.1.0^1,5>dodeca-2-en-9-ol
• CAS NO: 92760-17-3
• Molecular Weight: 220.355
• Mol File: 92760-17-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (1R,5S,8R,9R)-4,4,8-trimethylbicyclo<6.3.1.0^1,5>dodeca-2-en-9-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,5S,8R,9R)-4,4,8-trimethylbicyclo<6.3.1.0^1,5>dodeca-2-en-9-ol(92760-17-3)
• EPA Substance Registry System: (1R,5S,8R,9R)-4,4,8-trimethylbicyclo<6.3.1.0^1,5>dodeca-2-en-9-ol(92760-17-3)

Safety Data

• Hazardous Substances Data: 92760-17-3(Hazardous Substances Data)

Upstream product

• 60594-23-2 4α,5α-epoxyisocaryophyllene 
• 103475-43-0 caryophyllene-1β,10α-epoxide 
• 1139-30-6 Caryophyllene oxide 

Relevant articles and documents

MOLECULAR REARRANGEMENTS OF CARYOPHYLLENE AND ISOCARYOPHYLLENE 4,5-EPOXIDES IN SUPERACIDIC MEDIA

Enantiomeric stable carbocations were generated from the epimeric pair of optically active isocaryophyllene 4β,5β- and 4α,5α-epoxides in the superacid.The subsequent molecular rearrangement path is determined by participation of the ? and ? bonds in opening of the epoxide ring.For the case of caryophyllene 4β,5α- and 4α,5β-epoxides it was shown that rearrangement to compounds with the clovane or caryolane skeleton respectively is possible.The rearrangement of a compound of the caryophyllane type to compounds of the selinane group was realized for the first time.For the case of caryophyllene 4β,5α-epoxide it was shown that the generation temperature of the ions has a significant effect on the preferred position of the cationic center.