927670-18-6

Basic information

• Product Name: 3-Hexenal, 6-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, (3E)-
• CAS NO: 927670-18-6
• Molecular Formula: C22H28O2Si
• Molecular Weight: 352.549
• Mol File: 927670-18-6.mol

Chemical Properties

• CAS DataBase Reference: 3-Hexenal, 6-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, (3E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Hexenal, 6-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, (3E)-(927670-18-6)
• EPA Substance Registry System: 3-Hexenal, 6-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, (3E)-(927670-18-6)

Safety Data

• Hazardous Substances Data: 927670-18-6(Hazardous Substances Data)

Upstream product

• 58479-61-1 tert-butylchlorodiphenylsilane 
• 25126-93-6 dimethyl trans-3-hexene-1,6-dioate 
• 29311-53-3 (E)-3-hexene-1,6-dioic acid 
• 71655-17-9 (E)-3-hexen-1,6-diol 
• 927670-17-5 6-(tert-butyldiphenylsilanyloxy)hex-3-en-1-ol 

Downstream Products

• 927670-21-1 (2R,3R,5S)-(+)-5-(1(S)-bromobut-3-enyl)-2-[2-(tert-butyldiphenylsilanyloxy)ethyl]tetrahydrofuran-3-ol 
• 927670-19-7 (3E,6Z)-(tert-butyl)(deca-3,6,9-trienyloxy)diphenylsilane 

Relevant articles and documents

A biosynthetically-inspired synthesis of the tetrahydrofuran core of obtusallenes II and IV

Sharpless asymmetric dihydroxylation was regioselective for the frans olefin in an E vs Z vs terminal triene substrate. To test a biosynthetic hypothesis, the resulting diol underwent diastereoselective bromoetherification to provide the des-chloro core o