928028-38-0 Usage
Family
azirines
Chemical compound
2H-Azirine, 3-(3-buten-1-yl)-2,2-diphenyl-
Structure
contains a three-membered ring of one nitrogen and two carbon atoms, with a 3-(3-buten-1-yl) group and two phenyl groups attached
Reactivity
highly reactive due to strain in the three-membered ring
Applications
potential applications in organic synthesis and medicinal chemistry
Interest
subject of interest for researchers studying the behavior and properties of azirines in various chemical reactions
Check Digit Verification of cas no
The CAS Registry Mumber 928028-38-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 9,2,8,0,2 and 8 respectively; the second part has 2 digits, 3 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 928028-38:
(8*9)+(7*2)+(6*8)+(5*0)+(4*2)+(3*8)+(2*3)+(1*8)=180
180 % 10 = 0
So 928028-38-0 is a valid CAS Registry Number.
928028-38-0Relevant academic research and scientific papers
Fe(II)-catalyzed amination of aromatic C-H bonds via ring opening of 2 H-azirines: Synthesis of 2,3-disubstituted indoles
Jana, Samaresh,Clements, MacK D.,Sharp, Barry K.,Zheng, Nan
supporting information; scheme or table, p. 3736 - 3739 (2010/11/03)
A general method for the synthesis of 2,3-disubstituted indoles is described. The key feature of this method is the amination of aromatic C-H bonds via FeCl2-catalyzed ring opening of 2H-azirines. The method tolerates a variety of functional groups such as Br, F, NO2, OMe, CF3, OTBS, alkenes, and OPiv. The method can also be extended to synthesize azaindoles.
Rh(II)-catalyzed isomerization of 2-aryl-2H-azirines to 2,3-disubstituted indoles
Chiba, Shunsuke,Hattori, Gaku,Narasaka, Koichi
, p. 52 - 53 (2007/10/03)
Various 2,3-disubstituted indoles are synthesized by Rh 2(OCOCF3)4-catalyzed isomerization of 2-aryl-2H-azirines. Copyright
