92811-05-7Relevant academic research and scientific papers
A VICARIOUS AROMATIC SUBSTITUTION APPROACH TO AKLAVINONE FROM CHRYSAZIN
Murphy, Raymond A.,Cava, Michael P.
, p. 803 - 806 (2007/10/02)
The cheap, available dye-intermediate 1,8-dihydroxyanthraquinone (2) is converted efficiently to a useful aklavinone precursor (3).A Mitsunobu alkylation-Claisen rearrangement sequence and an unprecedented vicarious aromatic substitution on an anthraquino
ANTHRAQUINONE DYE INTERMEDIATES AS PRECURSORS OF AKLAVINONE-TYPE ANTHRACYCLINONES
Cava, Michael P.,Ahmed, Zareen,Benfaremo, Nicholas,Murphy, Raymond A.,O'Malley, Gerard J.
, p. 4767 - 4776 (2007/10/02)
The commercially available dye intermediates 1-hydroxyanthraquinone, 1-amino-2-methylanthraquinone and 1,8-dihydroxyanthraquinone (chrysazin) have been elaborated in a regiospecific manner into tetracyclic ketonitriles.The latter are potential precursors
