92830-64-3

Upstream product

• 90122-59-1 4-<2-(2-methoxyphenyl)ethyl>-3,5,5-trimethylcyclohex-2-enone 
• 90122-61-5 (+/-)-(1RS,2SR)-2-<2-(2-methoxyphenyl)ethyl>-1,3,3-trimethylcyclohexanecarbaldehyde 
• 90122-60-4 (+/-)-(1RS,2SR)-2-<2-(2-methoxyphenyl)-ethyl>-1,3,3-trimethyl-5-oxocyclohexanecarbonitrile 
• 110654-74-5 ethyl (+/-)-(1'RS,2'RS)-3-<-2'-<2-(2-methoxyphenyl)ethyl>-1',3',3'-trimethylcyclohexyl>prop-2(E)-enoate 
• 90122-62-6 (+/-)-(1'RS,2'RS)-3-<2'-<2-(2-methoxyphenyl)ethyl>-1',3',3'-trimethylcyxclohexyl>prop-2(E)-enol 
• 90122-63-7 (+/-)-(1''RS,2''RS)-6-<2-<3-hydroxyprop-1(E)-enyl>-2'',6'',6''-trimethylcyclohexylethyl>cyclohex-2-enone 
• 110654-72-3 (+/-)-(1RS,2SR)-5,5-ethylenedithio-2-<2-(2-methoxyphenyl)ethyl>-1,3,3-trimethylcyclohexanecarbaldehyde 
• 110654-71-2 (+/-)-(1RS,2SR)-5,5-ethylenedithio-2-<2-(2-methoxyphenyl)ethyl>-1,3,3-trimethylcyclohexanecarbonitrile 
• 90122-62-6 (E)-3-{(1R,2R)-2-[2-(2-Methoxy-phenyl)-ethyl]-1,3,3-trimethyl-cyclohexyl}-prop-2-en-1-ol 
• 90122-63-7 6-{2-[(1R,2R)-2-((E)-3-Hydroxy-propenyl)-2,6,6-trimethyl-cyclohexyl]-ethyl}-cyclohex-2-enone 

Downstream Products

• 92830-65-4 (+/-)-(1'RS,2'RS)-3-<1',3',3'-trimethyl-2'-<2-(2-oxocyclohex-3-enyl)ethyl>cyclohexyl>prop-2(E)-enoic acid 
• 90122-64-8 methyl (+/-)-(1'RS,2'RS)-3-<1',3',3'-trimethyl-2'-<2-(2-oxo-cyclohex-3-enyl)ethyl>cyclohexyl>prop-2(E)-enoate 
• 92830-65-4 (E)-3-{(1R,2R)-1,3,3-Trimethyl-2-[2-(2-oxo-cyclohex-3-enyl)-ethyl]-cyclohexyl}-acrylic acid 

Relevant academic research and scientific papers

An Enantioselective Total Synthesis of (+)-Atisirene by Intramolecular Double Michael Reaction

1,6-Conjugate addition of 2-methoxybenzylmagnesium bromide to 4-methylene-3,5,5-trimethylcyclohex-2-enone (7), followed by hydrocyanation, gave (+/-)-(1RS,2SR)-2--1,3,3-trimethyl-5-oxocyclohexanecarbonitrile (9), which was conver

INTRAMOLECULAR DOUBLE MICHAEL REACTION. PART II. SYNTHESIS OF ISOATISIRENE TYPE COMPOUND

Intramolecular double Michael reaction of the α,β-unsaturated enone ester (16), prepared from the dienone (5), stereoselectively gave the tetracyclic product (17), which was converted into the isoatisirene type compound (20).