928642-45-9

Upstream product

• 930-68-7 cyclohexenone 
• 407-38-5 2,2,2-trifluoroethyl trifluoroacetate 

Downstream Products

• 928642-46-0 (S)-6-triphenylsilylcyclohex-2-enone 
• 168301-25-5 3',5'-dimethoxy[1,1'-biphenyl]-2-ol 
• 2005-10-9 6H-benzo[c]chromen-6-one 
• 90-43-7 2-Phenylphenol 
• 1806-29-7 2,2'-dihydroxybiphenyl 
• 86610-20-0 4-(2-hydroxyphenyl)pyridine 
• 101043-55-4 2-(4-methylphenyl)phenol 
• 644-71-3 2-(phenylamino)phenol 
• 1613145-61-1 6-(phenylamino)cyclohex-2-enone 
• 1613145-53-1 2-((4-(tert-butyl)phenyl)amino)phenol 
• 58656-25-0 2-(mesitylamino)phenol 
• 1525599-07-8 2-((4-chlorophenyl)amino)phenol 
• 1613145-54-2 2-((4-(trifluoromethyl)phenyl)amino)phenol 
• 46425-95-0 o-(benzylamino)phenol 

Relevant academic research and scientific papers

Studies of the stereochemistry of [2+2]-photocycloaddition reactions of 2-cyclohexenones with olefins

(Chemical Equation Presented) Stereochemical studies of the photocycloaddition of a chiral α,β-enone and isobutylene lead to a working hypothesis for the geometry of the 3(π-π*) excited state of the enone.

Iodine-catalyzed synthesis of N, N ′-diaryl-o-phenylenediamines from cyclohexanones and anilines using DMSO and O2 as oxidants

A novel I2-catalyzed cross-dehydrogenative aromatization of cyclohexanones and anilines to synthesize N,N′-diaryl-o-phenylenediamines has been unprecedentedly developed with dimethyl sulfoxide and oxygen employed as mild terminal oxidants. To prove the rationality of the two separate dehydration steps of the proposed mechanism, a resulting I2-catalyzed cross-dehydrogenative aromatization of cyclohexenones and anilines to synthesize diarylamines has also been reported.

Silver(I)-catalyzed ring-contractive rearrangement: A new entry to 5-alkylidene-2-cyclopentenones

A novel silver(I)-catalyzed ring-contractive rearrangement of 5-substituted 6-diazo-2-cyclohexenones has been developed, providing a new and efficient access to 5-alkylidene-2-cyclopentenones. The AgOTf-catalyzed reaction proceeds through metal-carbenoid formation followed by endocyclic allyl [1,2] migration with excellent stereoselectivity and broad substrate scope.

A method for the catalytic enantioselective synthesis of 6-silylated 2-cyclohexenones

6-Silylated-2-cyclohexenones can be synthesized enantioselectively by hydrosilylation of the corresponding diazo-2-cyclohexenone in the presence of a chiral Rh(II) catalyst.