928673-82-9Relevant academic research and scientific papers
Mild conditions for Pd-catalyzed carboamination of N-protected hex-4-enylamines and 1-, 3-, and 4-substituted pent-4-enylamines. Scope, limitations, and mechanism of pyrrolidine formation
Bertrand, Myra Beaudoin,Neukom, Joshua D.,Wolfe, John P.
supporting information; experimental part, p. 8851 - 8860 (2009/04/11)
(Chemical Equation Presented) The use of the weak base Cs 2CO3 in Pd-catalyzed carboamination reactions of N-protected γ-aminoalkenes with aryl bromides leads to greatly increased tolerance of functional groups and alkene substitutio
Mild conditions for the synthesis of functionalized pyrrolidines via Pd-catalyzed carboamination reactions
Bertrand, Myra Beaudoin,Leathen, Matthew L.,Wolfe, John P.
, p. 457 - 460 (2007/10/03)
The palladium-catalyzed carboamination of N-protected y-aminoalkenes with aryl bromides and triflates has been achieved under new, mild reaction conditions using the weak base Cs2CO3 in dioxane solvent. These reactions tolerate a wid
