92885-10-4Relevant academic research and scientific papers
Studies on Conjugated Nitriles. V. Reaction of 3-Benzoyl- and 3-Ethoxycarbonylacrylonitriles with Enamines
Akiyama, Yasunobu,Abe, Junko,Takano, Tokuko,Kawasaki, Tomomi,Sakamoto, Masanori
, p. 2821 - 2824 (2007/10/02)
The reactions of 3-benzoylacrylonitrile (1a) with 3-amino-5,5-dimethyl-2-cyclohexenone (2) and ethyl 3-aminocrotonate (4) gave the corresponding pyridine derivatives, 3 and 5, respectively. 3-Ethoxycarbonylacrylonitrile (1b) also reacted with ethyl 3-benzylaminocrotonate (6) and 1-ethoxycarbonylmethylene-1,2,3,4-tetrahydroisoquinoline (9) to give the pyrrolin-5-one derivatives, 7 and 10, respectively.Keywords - acrylonitrile derivative; enamine derivative; pyridine derivative; pyrrolin-5-one derivative; stannic chloride.
