92905-18-5Relevant academic research and scientific papers
HAMMETT ANALYSIS OF ABSOLUTE CARBENE ADDITION RATE CONSTANTS
Moss, R.A.,Perez, L.A.,Turro, N.J.,Gould, I.R.,Hacker, N.P.
, p. 685 - 688 (1983)
Absolute rate constants were determined for the additions of 5 p-X-substituted ArCCl (X=CF3, Cl, H, CH3, CH3O) to tetramethylethylene, trimethylethylene, trans-pentene, and 1-hexene; good Hammett correlations were obtained with ρ= +1.4 - 1.6.
TIME-RESOLVED FLASH SPECTROSCOPIC INVESTIGATIONS OF THE REACTIONS OF SINGLET ARYLHALOCARBENES
Gould, I. R.,Turro, N. J.,Butcher, J.,Doubleday, C.,Hacker, N. P.,et al.
, p. 1587 - 1600 (2007/10/02)
The results of time-resolved laser flash spectrmetric studies of singlet arylhalocarbenes are reviewed.In particular, the absolute rate constants for reactions of phenylchlorocarbene and related carbenes with alkenes are summarized and systematized.The experiments described provide the basis for a detailed examination of carbenic reactivity-selectivity principles.The results of studies on the influence of temperature on the absolute rate constants for carbene reactions are consistent with the existence of transient carbene/alkene intermediates.
