92906-71-3Relevant articles and documents
Novel ruthenium-based metathesis catalysts containing electron-withdrawing ligands: Synthesis, immobilization, and reactivity
Halbach, Tobias S.,Mix, Stefan,Fischer, Dirk,Maechling, Simon,Krause, Jens O.,Sievers, Carsten,Blechert, Siegfried,Nuyken, Oskar,Buchmeiser, Michael R.
, p. 4687 - 4694 (2005)
The syntheses and reactivity of seven different ruthenium-based metathesis catalysts are described. Ru(CF3COO)2(PCy 3)(=CH-2-(2-PrO)C6H4) (1),Ru(CF 3COO)2(1,3-dimesityldihydroimi
Sequential catalysis: A metathesis/dihydroxylation sequence
Beligny, Samuel,Eibauer, Stefan,Maechling, Simon,Blechert, Siegfried
, p. 1900 - 1903 (2007/10/03)
(Chemical Equation Presented) A real step-saver: A single ruthenium-carbene complex catalyzes a sequence of two reactions, namely, a metathesis reaction (ring-closing or cross metathesis) and subsequent dihydroxylation of the newly formed double bond. A v
Unexpected results of a turnover number (TON) study utilising ruthenium-based olefin metathesis catalysts
Maechling, Simon,Zaja, Mirko,Blechert, Siegfried
, p. 1413 - 1422 (2007/10/03)
A turnover number (TON) study of ruthenium-based metathesis catalysts has been conducted for ring-closing metathesis (RCM) in dilute solution. Unexpectedly the results indicate that 1st generation metathesis catalysts can give higher TON in RCM
A novel polymer-supported arene-ruthenium complex for ring-closing olefin metathesis
Akiyama, Ryo,Kobayashi, Shu
, p. 2602 - 2604 (2007/10/03)
Styrene as ligand and support: An excellent polymer-supported ruthenium catalyst 1 has been developed in which the benzene rings of polystyrene are utilized as ligands to immobilize the ruthenium onto the polymer. In the presence of 1, ring-closing olefin