929083-72-7Relevant academic research and scientific papers
Divergent reactivity of an indole glucosinolate yields Lossen or Neber rearrangement products: The phytoalexin rapalexin A or a unique β-d-glucopyranose fused heterocycle
Pedras,To,Schatte
supporting information, p. 2505 - 2508 (2016/02/18)
Transformation of 1-t-Boc-4-methoxyindole-3-glucosinolate under acidic conditions yielded the potent phytoalexin rapalexin A, providing its first biomimetic synthesis via Lossen type rearrangement, while a novel 1-thioimidocarbonyl-β-d-glucopyranose heterocyclic system was obtained under basic conditions via Neber type rearrangement.
The first naturally occurring aromatic isothiocyanates, rapalexins A and B, are cruciferous phytoalexins
Pedras, M. Soledade C.,Zheng, Qing-An,Gadagi, Ravi S.
, p. 368 - 370 (2007/10/03)
The discovery of the first naturally occurring aromatic isothiocyanates, indole-3-isothiocyanates, their first synthesis, antimicrobial activity and proposed biogenetic origin in canola plants are reported. The Royal Society of Chemistry.
