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929097-92-7

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929097-92-7 Usage

Chemical Properties

Solid

Uses

(S)-3,3′-Bis(triphenylsilyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate can be used as a catalyst:In the synthesis of 1,3-dioxolochroman skeletons by reacting 3-methyl-2-vinylindoles with ortho-quinone methides.In the exo-selective cyclization of mupirocin methyl ester.In the kinetic resolution of cyclic aliphatic syn-1,3-diols, which are used as valuable building blocks.

Reactions

Chiral phosphoric acid catalyst used for the highly enantioselective Friedel-Crafts reaction of indoles with imines. Chiral phosphoric acid catalyst used for the highly enantioselective Friedel-Crafts reaction of pyrrole derivatives with N-acyl imines. Chiral phosphoric acid catalyst used for the enantioselective transfer hydrogenation of hydroxylactams providing enantioenriched tetrahydro-β-carbolines (in dioxane) at room temperature (up to 94% yield, 90% ee). [Rh2(OAc)4]/chiral phosphoric acid catalyst used for the enantioselective symmetric, three-component reaction of diazo compounds with imines and water yielding β-amino-α-hydroxy acid derivatives. Enantioselective desymmetrization of prochiral allenic diols via cooperative catalysis of Pd(OAc)2 and a chiral phosphoric acid.

Check Digit Verification of cas no

The CAS Registry Mumber 929097-92-7 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 9,2,9,0,9 and 7 respectively; the second part has 2 digits, 9 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 929097-92:
(8*9)+(7*2)+(6*9)+(5*0)+(4*9)+(3*7)+(2*9)+(1*2)=217
217 % 10 = 7
So 929097-92-7 is a valid CAS Registry Number.

929097-92-7 Well-known Company Product Price

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  • Aldrich

  • (680184)  (S)-3,3′-Bis(triphenylsilyl)-1,1′-binaphthyl-2,2′-diylhydrogenphosphate  96%

  • 929097-92-7

  • 680184-100MG

  • 3,569.67CNY

  • Detail

929097-92-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 14, 2017

Revision Date: Aug 14, 2017

1.Identification

1.1 GHS Product identifier

Product name 2,6-Bis(triphenylsilyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosph epin-4-ol 4-oxide

1.2 Other means of identification

Product number -
Other names S-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:929097-92-7 SDS

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