92912-07-7

Basic information

• Product Name: 4,8-Nonadienoic acid, methyl ester, (E)-
• CAS NO: 92912-07-7
• Molecular Formula: C10H16O2
• Molecular Weight: 168.236
• Mol File: 92912-07-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 4,8-Nonadienoic acid, methyl ester, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 4,8-Nonadienoic acid, methyl ester, (E)-(92912-07-7)
• EPA Substance Registry System: 4,8-Nonadienoic acid, methyl ester, (E)-(92912-07-7)

Safety Data

• Hazardous Substances Data: 92912-07-7(Hazardous Substances Data)

Upstream product

• 21963-38-2 5-vinyl-dihydrofuran-2(3H)-one 
• 420-37-1 trimethoxonium tetrafluoroborate 
• 762-72-1 allyl-trimethyl-silane 

Relevant articles and documents

Highly Regio- and Stereoselective Ring-Opening Reaction of γ-Alkenyl-γ-butyrolactones with Allysilanes in the Presence of Trimethyloxonium Salt Leading to Methyl 4,8-Alkadienoates

The reaction of γ-alkenyl-γ-butyrolactones with allylic trimethylsilanes in the presence of trimethyl-oxonium tetrafluoroborate proceeded regio- and stereoselectively with an allylic rearrangement of the substrate to afford methyl (E)-4,8-alkadienoates in high yields.On the other hand, the ring opening of 4-hexen-6-olide afforded exclusively methyl (Z)-4,8-alkadienoates in high yields.The synthetic utility of the reaction was demonstrated by the short step synthesis of β-sinensal and β-farnesene.