92912-10-2Relevant articles and documents
Synthetic studies toward pectenotoxin 2. Part II. Synthesis of the CDE and CDEF ring systems
Helmboldt, Hannes,Aho, Jatta E.,Pinko, Petri M.
supporting information; experimental part, p. 4183 - 4185 (2009/05/30)
(Chemical Equation Presented) A convergent synthesis of the CDE and CDEF ring systems of pectenotoxin-2 from C and F ring precursors is described.
HIGHLY REGIO- AND STEREOSELECTIVE RING-OPENING REACTION OF γ-ALKENYL-γ-BUTYROLACTONES USING ALLYLSILANES-TRIMETHYLOXONIUM SALT TO AFFORD METHYL (E)-4,8-ALKADIENOATES
Fujisawa, Tamotsu,Kawashima, Masatoshi,Ando, Shogo
, p. 3213 - 3216 (2007/10/02)
γ-Alkenyl-γ-butyrolactones reacted regio- and stereoselectively with allyltrimethylsilanes in the presence of trimethyloxonium tetrafluoroborate to afford methyl (E)-4,8-alkadienoates in high yields.Synthetic utility of the present reaction was demonstrated by the synthesis of β-sinensal.