92915-73-6

Basic information

• Product Name: C₁₆H₃₆N⁽¹⁺⁾*C₁₅H₁₀N₃O₃^(1-)
• CAS NO: 92915-73-6
• Molecular Weight: 522.731
• Mol File: 92915-73-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₆H₃₆N⁽¹⁺⁾*C₁₅H₁₀N₃O₃^(1-)(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₆H₃₆N⁽¹⁺⁾*C₁₅H₁₀N₃O₃^(1-)(92915-73-6)
• EPA Substance Registry System: C₁₆H₃₆N⁽¹⁺⁾*C₁₅H₁₀N₃O₃^(1-)(92915-73-6)

Safety Data

• Hazardous Substances Data: 92915-73-6(Hazardous Substances Data)

Upstream product

• 311-28-4 tetra-(n-butyl)ammonium iodide 
• 103-71-9 phenyl isocyanate 
• 39139-87-2 tetrabutylammonium isocyanate 

Relevant articles and documents

CHEMISTRY OF ONIUM CYANATES. COPOLYMERISATION WITH TDI YIELDING ONIUM POLYISOCYANURATES - POLYISOCYANATES

Owing to the lipophylic character of the tetraalkylonium cations many onium cyanates are soluble in aprotic organic solvents in which they show a high reactivity.In this paper we examine the reactions of onium cyanates (QNCO) with aromatic mono - and diisocyanates.Aromatic isocyanates react very rapidly with QNCO (co-trimerization) at room temperature to yield quantitetively onium diarylisocyanurates (IV) (S: Ac, DME).In some solvents (e.g.DCM) co-trimerization and trimerization to triarylisocyanurate (II) are observed (fig. 1).Onium polyisocyanurates polyisocyanates (scheme 1) are prepared from QNCO and diisocyanates (e.g.TDI), the first and rapid step being the co-trimerization to compound (V).In the absence of QNCO, (V) undergoes slow trimerization to (VII) (fig.2), but in the presence of QNCO co-trimerization to onium polyisocyanurate (VIII) occurs.However, the ionic heterocyclization is not perfectly selective, but is accompanied by the trimerization to triarylisocyanurates.The polymers synthesized from the TDI-QNCO systems are represented by the formula (IX), or in abbreviated form, (T)a(R)n(NCO)a+2.Experimental values of parameters a, n, and the average number of adjacent heterocyclic anions, , are presented in table 2.It is demonstrated that anionomers of high M.W. (a>10; n>100; ca. 5) and soluble in DCM can be prepared by this method.The important parameters in this polymerization are the nature of Q+ and that of the solvent (table 2).