92918-41-7Relevant academic research and scientific papers
Syntheses and Pyrolysis of Some α,α'-Bis(spiro(4-aryl-1-pyrazoline))cycloalkanones
Rao, CH. Bheemasankara,Raju, P. V. Narasimha
, p. 321 - 327 (2007/10/02)
α,α'-Bis(spiro(4-aryl-1-pyrazoline))cycloalkanones (IIa-m) have been synthesized through cycloaddition of diazomethane to α,α'-diarylidenecycloalkanones (Ia-m) which, in turn, are prepared by the aldol condensation of cyclopentanones and cyclohexanones with arylaldehydes and furfuraldehyde.Pyrolysis of bis-spiro compounds yields methyl dienes (VIa-c, l) with expanded ring systems in some cases and in one case formation of cyclopropane (VIII) without ring expansion is observed.
