929295-85-2

Basic information

• Product Name: 1-Cyclohexene-1-methanol, a-[4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-1-methylenebutyl]-
• CAS NO: 929295-85-2
• Molecular Formula: C18H34O2Si
• Molecular Weight: 310.552
• Mol File: 929295-85-2.mol

Chemical Properties

• CAS DataBase Reference: 1-Cyclohexene-1-methanol, a-[4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-1-methylenebutyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Cyclohexene-1-methanol, a-[4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-1-methylenebutyl]-(929295-85-2)
• EPA Substance Registry System: 1-Cyclohexene-1-methanol, a-[4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-1-methylenebutyl]-(929295-85-2)

Safety Data

• Hazardous Substances Data: 929295-85-2(Hazardous Substances Data)

Upstream product

• 18162-48-6 tert-butyldimethylsilyl chloride 
• 64180-78-5 4-bromopent-4-en-1-ol 
• 1192-88-7 1-cyclohexene-1-carboxaldehyde 
• 120001-35-6 ((4-bromopent-4-en-1-yl)oxy)(tert-butyl)dimethylsilane 

Downstream Products

• 929295-97-6 acetic acid 2-(3-azido-propyl)-1-cyclohex-1-enyl-allyl ester 
• 929295-93-2 acetic acid 1-cyclohex-1-enyl-2-(3-hydroxy-propyl)-allyl ester 
• 936747-30-7 2-(3-azido-propyl)-1-cyclohex-1-enyl-prop-2-en-1-ol 
• 929296-01-5 2-(3-azido-propyl)-1-cyclohex-1-enyl-propenone 
• 929295-89-6 acetic acid 2-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-1-cyclohex-1-enyl-allyl ester 

Relevant articles and documents

Intramolecular azide trapping of the Nazarov intermediate: Formation of peroxy-bridged indolizidinones via a deep-seated rearrangement and aerobic oxidation

Cross-conjugated dienones with pendent azide side chains undergo interrupted Nazarov trapping, leading to peroxy-bridged indolizidinones in good yields. This process is proposed to involve skeletal rearrangement of the initial trapping product, with loss