92939-47-4

Upstream product

• 937-31-5 (4-Nitrophenyl)acetylene 

Downstream Products

• 94567-96-1 C₈H₆⁽²⁾HNO₂ 
• 89039-48-5 C₁₅H₁₃⁽²⁾HClNO₂S 
• 89039-46-3 C₁₄H₁₀⁽²⁾HClN₂O₄S 
• 89039-36-1 C₁₅H₁₃⁽²⁾HClNO₂S 
• 89039-34-9 C₁₄H₁₀⁽²⁾HClN₂O₄S 
• 89039-14-5 1-[(1Z)-ethenyl-2-d]-4-nitrobenzene 
• 1450882-41-3 1-(ethenyl-d3)-4-nitrobenzene 
• 18462-38-9 (E)-1-nitro-4-(2-(phenylsulfonyl)vinyl)benzene 

Relevant academic research and scientific papers

Creating Dynamic Nanospaces in Solution by Cationic Cages as Multirole Catalytic Platform for Unconventional C(sp)?H Activation Beyond Enzyme Mimics

Herein we demonstrate that, based on the creation of dynamic nanospaces in solution by highly charged positive coordination cage of [Pd6(RuL3)8]28+, multirole and multi-way cage-confined catalysis is accomplisha

A practical and efficient method for late-stage deuteration of terminal alkynes with silver salt as catalyst

A practical and efficient H/D exchange method for selective deuteration of terminal alkynes was disclosed. The reaction was simply performed with CF3COOAg as catalyst at room temperature, affording products with high level of deuterium incorporation. The excellent site-selectivity and promising functional group tolerance of this protocol enabled deuteration of pharmaceuticals and nature product derivatives.

Mild deuteration method of terminal alkynes in heavy water using reusable basic resin

The mild and efficient deuteration of terminal alkynes (mono-substituted alkynes) proceeded in the presence of a basic anion exchange resin, WA30, which is a polystyrene polymer bearing a tertiary amine residue on the aromatic nuclei, in heavy water (D2O) at room temperature. WA30 could be easily removed by a simple filtration and repeatedly reused.

Chemoselective synthesis of unsymmetrical internal alkynes or vinyl sulfones via palladium-catalyzed cross-coupling reaction of sodium sulfinates with alkynes

A highly efficient and mild palladium-catalyzed cross-coupling of sodium sulfinates and alkynes for the selective synthesis of unsymmetrical internal alkynes and vinyl sulfones has been developed. This methodology has advantages of easily accessible starting materials, functional group tolerance and a wide range of substrates, which provides rapid access to alkynes and vinyl sulfones.

Site-selective deuterated-alkene synthesis with palladium on boron nitride

Heavy stuff: A triethylamine-mediated H-D exchange reaction for the conversion of unlabeled alkynes (1) into [D1]alkynes ([D 1]-1) in a mixture of D2O/THF has been developed. Furthermore, the efficient preparation of site-

Mild reaction conditions for the terminal deuteration of alkynes

Routinely employed syntheses of terminally deuterated alkynes often utilize strong bases (i.e., LDA, n-BuLi, or Grignard reagents) or low (i.e., -78 °C) or elevated (i.e., 56 °C) reaction temperatures; furthermore many of these procedures afford average y