929606-19-9

Upstream product

• 72824-04-5 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 100330-45-8 (+/-)-1-(2-Phenylethyl)-3-propynyl acetate 

Downstream Products

• 919284-03-0 (R)-4-methylene-1-phenylhex-5-en-3-yl propionate 
• 919284-01-8 (R)-5-phenylpent-1-yn-3-yl propionate 

Relevant academic research and scientific papers

Stereocontrol in palladium-catalyzed propargylic substitutions: Kinetic resolution to give enantioenriched 1,5-enynes and propargyl acetates

Kinetic resolution during the catalytic allyl-propargyl cross-coupling with chiral starting materials can be accomplished with a chiral palladium catalyst. These reactions offer ready access to enantiomerically enriched enyne products from simple, readily

Tandem enyne metathesis and Claisen rearrangement: A versatile approach to conjugated dienes of variable substitution patterns

To extend the versatility of the ruthenium carbene-promoted enyne metathesis, it was combined with an Ireland ester enolate Claisen rearrangement. This reaction sequence provided conjugated dienes of higher substitution pattern than that obtained through