92976-62-0

Upstream product

• 1125-99-1 1-(1-Cyclohexen-1-yl)pyrrolidine 
• 39082-53-6 1,1-bis(phenylsulfonyl)ethylene 
• 92976-57-3 4-[2-(2,2-Bis-benzenesulfonyl-ethyl)-cyclohex-1-enyl]-morpholine 
• 108-94-1 cyclohexanone 

Relevant academic research and scientific papers

Electrophilicities of bissulfonyl ethylenes

Kinetics of the reactions of bissulfonyl ethylenes with various carbanions, a sulfur ylide, and siloxyalkenes have been investigated photometrically at 20°C. The second-order rate constants have been combined with the known nucleophile- specific parameters N and sN for the nucleophiles to calculate the empirical electrophilicity parameters E of bissulfonyl ethylenes according to the linear free energy relationship log k(20°C)=s N(N+E). Structure-reactivity relationships are discussed, and it is shown that the electrophilicity parameters E derived in this work can be employed to define the synthetic potential of bissulfonyl ethylenes as Michael acceptors. Copyright

1,1-BIS(BENZENESULFONYL)ETHYLENE: A SYNTHETIC EQUIVALENT OF ETHYLENE 1,2-DIPOLE

1,1-Bis(benzenesulfonyl)ethylene (1) acts as a synthetic equivalent of ethylene 1,2-dipole as it gives with olefins products derived from a postulated dipolar reaction mechanism that can be readily desulfonylated into the formal ethylene adducts.

1,1-BIS(BENZENESULFONYL)ETHYLENE: A USEFUL SYNTHON FOR NEUTRAL HOMOLOGATION OF KETONES

1,1-Bis(benzenesulfonyl)ethylene (1) is a versatile building block in organic synthesis since it reacts under neutral conditions with enolizable ketones to afford adducts that can be subjected to a variety of synthetic transformations.