930117-57-0

Basic information

• Product Name: (2E)-[(4R,5R,6S)-4,5-dihydroxy-6-{[2,3,4,6-tetrakis-O-(2-methylpropanoyl)-β-D-glucopyranosyl]oxy}-cyclohex-2-en-1-ylidene]ethanenitrile
• Synonyms: (2E)-[(4R,5R,6S)-4,5-dihydroxy-6-{[2,3,4,6-tetrakis-O-(2-methylpropanoyl)-β-D-glucopyranosyl]oxy}-cyclohex-2-en-1-ylidene]ethanenitrile
• CAS NO: 930117-57-0
• Molecular Weight: 609.671
• Mol File: 930117-57-0.mol

Chemical Properties

• CAS DataBase Reference: (2E)-[(4R,5R,6S)-4,5-dihydroxy-6-{[2,3,4,6-tetrakis-O-(2-methylpropanoyl)-β-D-glucopyranosyl]oxy}-cyclohex-2-en-1-ylidene]ethanenitrile(CAS DataBase Reference)
• NIST Chemistry Reference: (2E)-[(4R,5R,6S)-4,5-dihydroxy-6-{[2,3,4,6-tetrakis-O-(2-methylpropanoyl)-β-D-glucopyranosyl]oxy}-cyclohex-2-en-1-ylidene]ethanenitrile(930117-57-0)
• EPA Substance Registry System: (2E)-[(4R,5R,6S)-4,5-dihydroxy-6-{[2,3,4,6-tetrakis-O-(2-methylpropanoyl)-β-D-glucopyranosyl]oxy}-cyclohex-2-en-1-ylidene]ethanenitrile(930117-57-0)

Safety Data

• Hazardous Substances Data: 930117-57-0(Hazardous Substances Data)

Upstream product

• 930117-56-9 (2E)-{(4R,5R,6S)-4,5-(cyclohexylidenedioxy)-6-[(2,3,4,6-tetra-O-isobutyryl-β-D-glucopyranosyl)oxy]-cyclohex-2-en-1-ylidene}ethanenitrile 
• 930117-55-8 (2E)-[(4R,5S,6S)-4,5-(cyclohexylidenedioxy)-6-hydroxycyclohex-2-en-1-ylidene]ethanenitrile 

Downstream Products

• 84799-67-7 hexaacetate of (Z)-6α-(β-D-glucosyloxy)-4α,5α-dihydroxy-2-cyclohexene-Δ^1,α-acetonitrile 
• 84799-31-5 (Z)-6α-(β-D-glucosyloxy)-4α,5α-dihydroxy-2-cyclohexene-Δ^1,α-acetonitrile 

Relevant articles and documents

Total synthesis of (2Z)-[(4R,5R,6S)-6-(β-D-glucopyranosyloxy)-4,5- dihydroxycyclohex-2-en-1-ylidene]ethanenitrile, a cyanoglucoside from Ilex warburgii

The total synthesis of the noncyanogenic cyanoglucoside 1, originally isolated from Ilex warburgii, was achieved in nine steps (9% overall yield), starting from an optically pure Diels-Alder adduct ((+)-3). The key step of the synthesis, the glycosidation