93040-53-0Relevant academic research and scientific papers
Iodobenzene-catalysed iodolactonisation using sodium perborate monohydrate as oxidant
Liu, Hongjun,Tan, Choon-Hong
, p. 8220 - 8222 (2007)
A convenient approach has been developed for iodolactonisation using iodobenzene as catalyst. The active reagent was generated in situ with tetra-n-butylammonium iodide (TBAI) and hypervalent iodine reagent, diacetoxyiodobenzene (PIDA). PIDA, in turn, was generated in situ using a catalytic amount of iodobenzene with sodium perborate monohydrate as the stoichiometric oxidant. A variety of olefinic acids including δ-pentenoic acids, δ-pentynoic acids and δ-hexynoic acid gave high yields of lactones using this methodology.
Ynenol Lactones: Synthesis and Investigation of Reactions Relevant to Their Inactivation of Serine Proteases
Spencer, Robin W.,Tam, Tim Fat,Thomas, Everton,Robinson, Valerie J.,Krantz, Allen
, p. 5589 - 5597 (2007/10/02)
The syntheses of ynenol lactones which are designed as serine protease suicide substrates have b
